(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
CAS: 565184-29-4
Molecular Formula: C42H48FeP210*
(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene - Names and Identifiers
| Name | (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine |
| Synonyms | (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine (1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene (R)-1-[(R)-1- (Dicyclohexylphosphino)ethyl]- 2-[2- (diphenylphosphino)phenyl]ferro cene Ferrocene,1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]-, (1S)- (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine, Walphos SL-W003-1 |
| CAS | 565184-29-4 |
(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene - Physico-chemical Properties
| Molecular Formula | C42H48FeP210* |
| Molar Mass | 670.623042 |
| Specific Rotation(α) | -8° ±2° (c 0.5, CHCl3) |
| Appearance | Powder |
| Color | orange |
(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene - Introduction
(R)-(-)-1-[(R)-2-(2 '-diphenylphosphinophenyl) ferrocene] ethyldicyclohexylphosphine is an organic ligand whose chemical name is [(R)-2-(diphenylphosphinophenyl)ferrocenyl]-ethyl-dicyclohexylphosphine.
The following are some of the properties and uses of the compound:
Nature:
-Appearance: solid powder
-Solubility: Soluble in common organic solvents such as chloroform, toluene and dichloromethane
Use:
-As a chiral ligand: Since the compound contains a chiral center, it can be used as a catalyst and ligand in organic synthesis.
-Synthesis of metal organic compounds: This compound can react with metals to form metal organic compounds.
Preparation Method:
-can be synthesized by synthetic steps. A general synthetic method involves reacting [racemic-(dicyclohexylphosphino)ferrocenyl]boronate with 2-bromodiphenylphosphinobenzene in the presence of a base in a sodium acetate system to produce (R)-(-)-1-[(R)-2-(2 '-diphenylphosphinophenyl) ferrocene] ethyldicyclohexylphosphine.
Safety Information:
-Appropriate safety precautions, including gloves and goggles, are required when handling the compound.
-Since the compound has not been widely studied for its effects on human health and the environment, more detailed safety information still requires further experimental research.
The following are some of the properties and uses of the compound:
Nature:
-Appearance: solid powder
-Solubility: Soluble in common organic solvents such as chloroform, toluene and dichloromethane
Use:
-As a chiral ligand: Since the compound contains a chiral center, it can be used as a catalyst and ligand in organic synthesis.
-Synthesis of metal organic compounds: This compound can react with metals to form metal organic compounds.
Preparation Method:
-can be synthesized by synthetic steps. A general synthetic method involves reacting [racemic-(dicyclohexylphosphino)ferrocenyl]boronate with 2-bromodiphenylphosphinobenzene in the presence of a base in a sodium acetate system to produce (R)-(-)-1-[(R)-2-(2 '-diphenylphosphinophenyl) ferrocene] ethyldicyclohexylphosphine.
Safety Information:
-Appropriate safety precautions, including gloves and goggles, are required when handling the compound.
-Since the compound has not been widely studied for its effects on human health and the environment, more detailed safety information still requires further experimental research.
Last Update：2024-04-09 21:04:16
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